In Ironman 2 when Justin Hammer was revealing her armors at that time he also introduced with War Machine and at that time Tony comes there and was saying Rodhey to go from here but he talk to much upto that Ivan vanko target Tony and also lock War Machine on Tony so all armor go with and was trying to kill her and then Natasha Romanoff was trying to unlock War machine so he can't target Tony after that Tony and war machine both destroyed all armors and with its different technique they defeat Ivan Vanko.
9) Battle of Gulmira :-
When Tony realize that something is going wrong with her company on her back so he think to do something and then he wear armor and go to Gulmira where terrorist was attacking on civilians and the we see her Landings and then Tony fights with them and destroy her Stark Industries Weapons and in this Tank attack on Tony and he fall down but then also he even don't get hurt and then with one missile he blasts That Tank and ho from there.
8) Battle on the Norco:-
When Rhodey and Tony was tracing Aldrich killian they come to Norco and where Tony shows rhodey his Iron legion where her all armor was there but only Mark 42 was not in it and then Tony changes so many suit when fighting with Aldrich Killian in between all these he thinks pepper is died and after that he fight again with Aldrich Killian and then Mark 42 comes there but it's entry was bad but also then Tony puts that Mark 42 on Aldrich Killian and Mark 42 get destroyed also with it Aldrich Killian died.
7) Battle at Airport:-
In Civil war when Tony came to know Escape plan of Steve then He with Rhodey goes to Airport with his team and Said to Steve that he give him Bucky buy when Steve say no yo Tony then Tony calls Spiderman and then Spiderman Takes her sheild and after that Both Avenger team start to Fight in this fight Tony only wants to Detain opposite team but when Rhodey got injured and Captain escape successfully.
6) Battle of New York:-
Battle of New York was start by Tony when Remaining Avengers were not ready at that time Tony was talking with Loki and after that also he alone was handling Chituris Army and when Missile was put toward city at that time also he take that Missile and Take into space and he fall from Portal.
5) Battle of sokovia:-
In this movie also Tony first comes toward his villian where remaining Avengers were taking people to the safe place and at that time Tony was trying to understand Ultrons Mission and after sometime he came to know he can only save the sokovian people when he will destroy the Sokovia which was flying and at that time Sheild comes there and people got safe and then Avengers start to fight with Ultrons Army and Ultron and when people get safed then Tony and Thor Destroy Flying Sokovia.
4) Hulk vs Hulk buster :-
In Age of Ultron when Hulk was not in control then Tony brings her Hulk buster suit from his Satellite and then he fights with Hulk and in this fight he owns a Building and destroy that building and also he breaks Hulk teeth and at last he give punch to Hulk and Hulk got sleep.
3) Battle at the Hydra Facility:-
In captain America Civil war as we see how Helmut Zemo put fight between Avengers and in that fight some get injured also and Helmut Zemo also put fight between Captain and Tony at Hydra Facility and then Tony tries to kill Bucky and captain was trying to save her and they also fight, in this fight Tony got defeat cause he just want bucky.
2) Battle of Earth :-
It was not Tonys best fight and it was Avengers best fight and here the scene when Thor hits Tonys armor and when his armor generate energy and he put it on Thanos but Thanos defend himself with his sword. Due to Tony's five year gap he was not able to fight toughly so we don't see her to many fight moment but at last when he see toward doctor Strange he came to know what he have to do and then he Snap with taking all six Infinity stones on his hand and he Sacrifice Him self.
1) Battle at Titan :-
In Infinity war when some guardians get injured, spiderman was catching some guardian and also Doctor Strange was injured then Tony stands In front of Thanos and he give Tough Fight to Thanos and also where he make Thanos Bleed but then Thanos beat him and injured Tony and he said to Tony that "Hope they we remember you".
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